PVA enhances adhesive performance through hydrogen bonding and film-forming ability. Its hydroxyl groups bond with polar substrates like paper, wood, and glass, creating strong primary bonds. PVA adhesives dry to form continuous, flexible films that resist shrinkage, ideal for bookbinding and cardboard lamination. Adjusting hydrolysis degree tunes water resistance: fully hydrolyzed PVA (99% DH) forms water-resistant bonds in woodworking, while partially hydrolyzed (88% DH) is suitable for water-soluble adhesives. Adding plasticizers like glycerol improves flexibility for leather bonding. PVA’s high solid content allows thick coatings, reducing application layers. Its quick drying (10-15 minutes) boosts production efficiency in packaging lines, while thermal stability enables use in hot-melt adhesives.